Ioannis D. Kostas - Publications

2008

I.D. Kostas*
"Chiral Bidentate Monophosphorus Ligands: Hybrid Monophosphorus Ligands - Other P/N-Ligands". In Phosphorus Ligands in Asymmetric Catalysis - Synthesis and Applications, A. Börner (Ed.), Wiley-VCH, Weinheim, 2008, part IV, chapter 1.2.

I.D. Kostas*, K.A. Vallianatou, J. Holz, A. Borner*
Tetrahedron Lett. 2008, 49(2), 331-334
"A new easily accessible chiral phosphite-phosphoramidite ligand based on 2-anilinoethanol and R-BINOL moieties for Rh-catalyzed asymmetric olefin hydrogenation"

D. Kovala-Demertzi*, N. Kourkoumelis*, K. Derlat, J. Michalak, F.J. Andreadaki, I.D. Kostas*
Inorg. Chim. Acta 2008, 361(5), 1562-1565
"Thiosemicarbazone-derivatised palladium nanoparticles as efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides with phenylboronic acid"

I.D. Kostas*
Curr. Org. Synth. 2008, in press
"Recent Advances on P,N-Containing Ligands for Transition-Metal Homogeneous Catalysis"

2007

I.D. Kostas*, A.G. Coutsolelos*, G. Charalambidis, A. Skondra
Tetrahedron Lett. 2007, 48(38), 6688-6691
"The first use of porphyrins as catalysts in cross-coupling reactions: a water-soluble palladium complex with a porphyrin ligand as an efficient catalyst precursor or the Suzuki-Miyaura reaction in aqueous media under aerobic conditions"

K.A. Chatziapostolou, K.A. Vallianatou, A. Grigoropoulos, C.P. Raptopoulou, A. Terzis, I.D. Kostas*,
P. Kyritsis*, G. Pneumatikakis
J. Organomet. Chem. 2007, 692(19), 4129-4138
"Synthesis and characterization of new Rh ^I complexes bearing CO, PPh3 and chelating P,O- or Se,Se-ligands. Application to hydroformylation of styrene''

2006

K.A. Vallianatou, I.D. Kostas*, J. Holz, A. Borner
Tetrahedron Lett. 2006, 47(45), 7947-7950
''Me-AnilaPhos: A new chiral phosphine-phosphoramidite ligand for a highly efficient Rh-catalyzed asymmetric olefin hydrogenation''

E.I. Tolis, K.A. Vallianatou, F.J. Andreadaki, I.D. Kostas*
Appl. Organomet. Chem. 2006, 20(5), 335-337
''A new rhodium complex with a nitrogen-containing bis(phosphine oxide) ligand as an efficient catalyst for the hydroformylation of styrene''

I.D. Kostas*, G.A. Heropoulos*, D. Kovala-Demertzi*, P.N. Yadav, J.P. Jasinski, M.A. Demertzis, F.J. Andreadaki, G. Vo-Thanh, A. Petit, A. Loupy
Tetrahedron Lett. 2006, 47(26), 4403-4407
''Microwave-promoted Suzuki-Miyaura cross-coupling of aryl halides with phenylboronic acid under aerobic conditions catalyzed by a new palladium complex with a thiosemicarbazone ligand''

I.D. Kostas*, B.R. Steele*, A. Terzis, S.V. Amosova, A.V. Martynov, N.A. Makhaeva
Eur. J. Inorg. Chem. 2006, (13), 2642-2646
''New Palladium Complexes with S- or Se-Containing Schiff-Base Ligands as Efficient Catalysts for the Suzuki-Miyaura Cross-Coupling Reaction of Aryl Bromides with Phenylboronic Acid under Aerobic Conditions''

N.G. Oikonomakos*, M.N. Kosmopoulou, D.D. Leonidas, E.D. Chrysina, C. Tiraidis, N. Bischler, K.E. Tsitsanou, S.E. Zographos, I.D. Kostas, G. Eisenbrand
''Indirubin and indigo analogues as potential inhibitors of glycogenolysis: structural basis of glycogen phosphorylase inhibition''. In Indirubin, the red shape of indigo, L. Meijer, N. Guyard, L.A. Skaltsounis, G. Eisenbrand (eds.):
Editions ''Life in Progress'', Roscoff, 2006, Chapter 18, 177-189.

2005

I.D. Kostas*, K.A. Vallianatou, J. Holz, A. Borner
Appl. Organomet. Chem. 2005, 19(10), 1090-1095
''Rhodium complexes with a new chiral nitrogen-containing BINOL-based diphosphite or phosphonite ligand: synthesis and application to hydroformylation of styrene and/or hydrogenation of prochiral olefins''

N.V. Dubrovina*, V.I. Tararov, A. Monsees, A. Spannenberg, I.D. Kostas, A. Borner*
Tetrahedron: Asymmetry 2005, 16(22), 3640-3649
''New chiral 1,3-diphosphine ligands for Rh-catalyzed enantioselective hydrogenation: a search for electronic effects''

I.D. Kostas*, F.J. Andreadaki, D. Kovala-Demertzi*, C. Prentjas, M.A. Demertzis
Tetrahedron Lett. 2005, 46(12), 1967-1970
''Suzuki-Miyaura cross-coupling reaction of aryl bromides and chlorides with phenylboronic acid under aerobic conditions catalyzed by palladium complexes with thiosemicarbazone ligands''

S.V. Amosova*, N.A. Makhaeva, A.V. Martynov, V.A. Potapov, B.R. Steele, I.D. Kostas
Synthesis 2005, (10), 1641-1648
''Terminal organochalcogenoethyl- and -propylamines and their Schiff base derivatives''

N.G. Oikonomakos*, M.N. Kosmopoulou, E.D. Chrysina, D.D. Leonidas, I.D. Kostas, K.U. Wendt, T. Klabunde, E. Defossa
Protein Sci. 2005, 14(7), 1760-1771
''Crystallographic studies on acyl ureas, a new class of glycogen phosphorylase inhibitors, as potential antidiabetic drugs''

2004

I.D. Kostas*, K.A. Vallianatou, P. Kyritsis*, J. Zednik, J. Vohlidal*
Inorg. Chim. Acta 2004, 357, 3084-3088
''Hydroformylation of alkenes catalyzed by new dinuclear aryloxide- and carboxylate-bridged rhodium complexes''

I.D. Kostas*, B.R. Steele, F.J. Andreadaki, V.A. Potapov
Inorg. Chim. Acta 2004, 357, 2850-2854
''Rhodium complexes possessing S-phosphinite ligands with or without an amino group. Application to hydroformylation of styrene''

A.V. Martynov*, N.A. Makhaeva, V.A. Potapov, S.V. Amosova, B.R. Steele, I.D. Kostas
Phosphorus Sulfur 2004, 179(7), 1373-1380
''Reduction of Terminal Organylchalcogeno Phosphonates as a Way to Prepare Primary Organylchalcogeno Phosphines''

D. Kovala-Demertzi*, P.N. Yadav, M.A. Demertzis, J.P. Jasiski, F.J. Andreadaki, I.D. Kostas*
Tetrahedron Lett. 2004, 45(14), 2923-2926
''First use of a palladium complex with a thiosemicarbazone ligand as catalyst precursor for the Heck reaction''

2003

I.D. Kostas*, B.R. Steele*, A. Terzis, S. V. Amosova
Tetrahedron 2003, 59(19), 3467-3473
''A palladium complex with a new hemilabile amino- and sulfur-containing phosphinite ligand as an efficient catalyst for the Heck reaction of aryl bromides with styrene. The effect of the amino group''

I.D. Kostas*
Inorg. Chim. Acta 2003, 355, 424-427
''Synthesis of new nitrogen-containing phosphinite and phosphine-phosphinite ligands. Application to rhodium-catalyzed hydroformylation of styrene''

2002

M.T. Reetz*, I.D. Kostas, S.R. Waldvogel
Inorg. Chem. Commun. 2002, 5(4), 252-254
''Synthesis of a gold(I) complex with a (thio)phosphine-modified β-cyclodextrin''

2001

I.D. Kostas*
J. Organomet. Chem. 2001, 626(1-2), 221-226
''Synthesis of new rhodium complexes with a hemilabile nitrogen-containing bis(phosphinite) or bis(phosphine) ligand. Application to hydroformylation of styrene''

I.D. Kostas*
J. Organomet. Chem. 2001, 634(1), 90-98
''Synthesis of a tetramethoxy and an amphiphilic tetrahydroxy hemilabile N,P,N-ligand. Coordination behavior towards rhodium(I) and application to hydroformylation of styrene or hydrogenation of trans-cinnamaldehyde''

1999

I.D. Kostas, O.S. Akkerman, F. Bickelhaupt*, N. Veldman, A.L. Spek
J. Organomet. Chem. 1999, 572, 93-104
''Intraannular functionalization of the 1,3-phenylene-19-crown-6 system via bromine-lithium exchange''

I.D. Kostas*, C.G. Screttas*
J. Organomet. Chem. 1999, 585(1), 1-6
''New rhodium complexes with P,N-ligands possessing a hydroxy or methoxy group. Synthesis, characterization and application to hydroformylation of styrene''

C.S. Salteris, I.D. Kostas, M. Micha-Screttas, G.A. Heropoulos, C.G. Screttas*, A. Terzis
J. Org. Chem. 1999, 64(15), 5589-5592
''Ortho-Directed Lithiation of ω-Phenoxy Alcohols''

C.S. Salteris, I.D. Kostas, M. Micha-Screttas, G.A. Heropoulos, C.G. Screttas*, A. Terzis
Main Group Met. Chem. 1999, 22(7), 427-434
''ortho-Directed Lithiation of ω-Phenoxyalkanethiols and N,N-Dimethyl-ω-phenoxyalkylamines. Crystal Structure of Bis[o-[(2-dimethylamino)ethoxy]phenyl]-mercury''

I.D. Kostas*
J. Chem. Res. (S) 1999, (10), 630-631
''Hydroaminomethylation of Styrene with Morpholine Catalysed by a Rhodium Complex with a Phosphino Amino Alcohol Ligand''

C.S. Salteris, I.D. Kostas, M. Micha-Screttas, B.R. Steele, G.A. Heropoulos, C.G. Screttas*, A. Terzis
J. Organomet. Chem. 1999, 590(1), 63-70
''Synthesis of lithium ω-(m- and p-lithiophenoxy)alkoxides modified with magnesium 2-ethoxyethoxide. Crystal structures of bis[4-(2-hydroxyethoxy)phenyl]mercury and bis[4-(3-hydroxypropoxy)phenyl]mercury''

1998

I.D. Kostas*
''Applied Homogeneous Catalysis'', in ''Contemporary Organic Chemistry and Applications'' (in Greek), National Hellenic Research Foundation, Institute of Organic and Pharmaceutical Chemistry, Athens 1998, pp. 27-48

1997

I.D. Kostas, C.G. Screttas*
J. Org. Chem. 1997, 62(16), 5575-5577
"Synthesis and Applications of Tetrahydrofuran-Stable Substituted 3-(Lithioxyalkyl)- and 4-(Lithioxyalkyl)lithiums, Modified with Magnesium 2-Ethoxyethoxide"

I.D. Kostas, C.G. Screttas*, C.P. Raptopoulou, A. Terzis
Tetrahedron Lett. 1997, 38(50), 8761-8764
"A Remarkable Tendency of o-Lithio-N-(2-lithiooxyethyl)-N-methyl-aniline to Form Heterocyclic Derivatives by its Reaction with Dichlorodialkylsilanes or Silicon Tetrachloride. Synthesis of 2,5,1-Benzoxazasilepines and of the Silaspiro Analogue"

I.D. Kostas, C.G. Screttas*
Main Group Met. Chem. 1997, 20(12), 787-790
"Synthesis of Tetrahydrofuran-Stable ω-Lithioxy-azaalkyllithiums"

1996

I.D. Kostas, G-J.M. Gruter, O.S. Akkerman, F. Bickelhaupt*, H. Kooijman, W.J.J. Smeets, A.L. Spek
Organometallics 1996, 15(21), 4450-4458
"Functionalization of 1,3-Phenylene-16-crown-5 via Direct Lithiation"

1991

I.D. Kostas*
PhD Thesis, University of Athens, Athens 1991
''Metal alkoxide modified organolithium reagents. Synthesis and stabilization of substituted lithioxyalkylithiums including the aza-analogues, in tetrahydrofuran, in the presence of magnesium 2-ethoxyethoxide'' (in Greek)

1986

I.D. Kostas*
Undergraduate Thesis in Chemistry, Aristotle University of Thessaloniki, Thessaloniki 1986
''1,3-Dipolar cycloaddition of nitrile oxides to 2,6-dibenzylidenecycloexanone'' (in Greek)